A precursor of stress corrosion cracking in chloride bearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. The combination of tensile stress and a specific corrosive environment can crack stainless steels. Chloride induced stress corrosion cracking of stainless. Although no stainless steel grade is totally immune. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides.
Certain austenitic stainless steels and aluminium alloys crack in the presence of chlorides. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. This mode of attack is termed stress corrosion cracking scc. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions. The hsl research report 902 reference 1 covers the susceptibility of stainless steel to ciscc in some detail and links to other research papers and published documents. Chloride stress corrosion cracking in austenitic stainless. Im not a corrosion engineer, but it seems to me that if we replace these vessels with an austenitic stainless, it is an almost sure bet that they will soon start to.
Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Stress corrosion cracking facts and how to reduce the. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical. This limits the usefulness of austenitic stainless steel for containing.
Pdf chloride induced stress corrosion cracking of type. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Why are austenitic stainless steels more susceptible to. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Chloride stress corrosion cracking inspectioneering. Addition of nitrite to the chloride solution, which is reported to have inhibitive influence on corrosion of stainless steels, was found to increase. The most pitting resistance is seen to be for the nitronic 50 stainless steel. Stress corrosion cracking facts and how to reduce the risk. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. If the atmosphere contains halides this can leave any stainless steel susceptible to chloride stress corrosion cracking ciscc. Stress corrosion cracking of an austenitic stainless steel in.
Stress corrosion cracking scc is a common issue with many specialty alloys. Chloride stress corrosion cracking in austenitic stainless steel. Although austenitic 300 series ss are prone to chloride stress cracking in the harsh chloride environment above 60c and your operation is at 100c which is. Chloride stress corrosion cracking ssina specialty steel. In aqueous chloride environments austenitic stainless steels and many nickel based alloys are common to perform poorly. What is temperature it is more important than concentration of chloride and anything higher than room temperature higher is worse. Chloride stress corrosion cracking metal and metallurgy. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting.
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